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Substituent effects on the acidity of the acetylenic proton: An ab initio study

✍ Scribed by M.F. Powell; M.R. Peterson; I.G. Csizmadia


Book ID
119116064
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
873 KB
Volume
92
Category
Article
ISSN
0166-1280

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An Ab Initio Study of Substituent Effect
✍ Alessandro Bongini; Zhining Xia; Mauro Panunzio πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 127 KB πŸ‘ 1 views

## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc