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An Ab initio study of substituent effects on 12-shifts in radicals

✍ Scribed by Charles E. Hudson; David J. McAdoo


Book ID
104203279
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
266 KB
Volume
46
Category
Article
ISSN
0040-4020

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An Ab Initio Study of Substituent Effect
✍ Alessandro Bongini; Zhining Xia; Mauro Panunzio πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 127 KB πŸ‘ 1 views

## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc