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Ab initio study of α- and β- silyl substituent effects on vinyl radicals

✍ Scribed by S. Lalitha; Jayaraman Chandrasekhar

Book ID
112906928
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1994
Tongue
English
Weight
445 KB
Volume
106
Category
Article
ISSN
0253-4134

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✍ Alessandro Bongini; Zhining Xia; Mauro Panunzio 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB 👁 1 views

## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc