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Theoretical study on the effect of α-substituents on the properties of vinyl radicals

✍ Scribed by Maurizio Guerra


Book ID
114996511
Publisher
Springer Netherlands
Year
1996
Tongue
English
Weight
605 KB
Volume
22
Category
Article
ISSN
0922-6168

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Theoretical studies of the effects of α-
✍ Ikchoon Lee; Soo Chung Dong; Jin Jung Hak 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 393 KB

Our AM1 results show that : ( i ) Electron-withdrawing p&z effect of u -substitueuts leads to tbeamodynamic destabilization, B Al? > 0, of bensylic carimcations. (ii) The increments of positive charge on C. aud on metboxy-0 accompauying the csrbocation formation are linearly correlated with the elec