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Effect of Substituents on the Structure of the Vinyl Radical: Calculations and Experiments

✍ Scribed by Galli, Carlo; Guarnieri, Alessandra; Koch, Heinz; Mencarelli, Paolo; Rappoport, Zvi


Book ID
121503593
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
334 KB
Volume
62
Category
Article
ISSN
0022-3263

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Effect of substituents on the radical co
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## Abstract Radical copolymerizations of ring‐substituted __trans__‐cinnamonitriles with olefins such as styrene and acrylonitrile were studied at 60Β°C. The copolymerization parameters of cinnamonitriles (M~1~) in the copolymerizations with styrene (M~2~) were determined to be __r__~1~ = 0,01 to 0,