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An ab Initio Study of Substituent Effects in [1,3]-Hydrogen Shifts

✍ Scribed by Hudson, Charles E.; McAdoo, David J.


Book ID
127324741
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
108 KB
Volume
68
Category
Article
ISSN
0022-3263

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An Ab Initio Study of Substituent Effect
✍ Alessandro Bongini; Zhining Xia; Mauro Panunzio πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 127 KB πŸ‘ 1 views

## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc