Study of Pt(II)-cyclic amines complexes of the types cis- and trans-Pt(amine)2I2 and cis- and trans-Pt(amine)2(NO3)2 and their aqueous products by
β Scribed by Fernande D. Rochon; Viorel Buculei
- Book ID
- 111713003
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 274 KB
- Volume
- 358
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
## Abstract ^13^Cβ and ^195^PtβNMR. spectra for the complexes __trans__βPtCl~2~(amine)(CH~2~ο£ΎCH~2~) have been measured. For amine = (__S__)β__N__βmethylβΞ±βmethylbenzylamine the two diastereomers present may be distinguished from the values ^3^__J__(Pt,C). The ^195^Ptβchemical shift is shown to be s
The i.r. spectra (4000-80 cm-') of the newly-reported complexes cisand trans-[Pt(pzhXr] (pz = pyrazine; X = Cl, Br, I, N02) are discussed. Assignments for internal l&and modes are based on the effects of ligand deuteration. Assignments of metal-l&and modes are based on the effects of halide substitu