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Study of Pt(II)-cyclic amines complexes of the types cis- and trans-Pt(amine)2I2 and cis- and trans-Pt(amine)2(NO3)2 and their aqueous products by

✍ Scribed by Fernande D. Rochon; Viorel Buculei


Book ID
111713003
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
274 KB
Volume
358
Category
Article
ISSN
0020-1693

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## Abstract ^13^C‐ and ^195^Pt‐NMR. spectra for the complexes __trans__‐PtCl~2~(amine)(CH~2~ο£ΎCH~2~) have been measured. For amine = (__S__)‐__N__‐methyl‐α‐methylbenzylamine the two diastereomers present may be distinguished from the values ^3^__J__(Pt,C). The ^195^Pt‐chemical shift is shown to be s

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The i.r. spectra (4000-80 cm-') of the newly-reported complexes cisand trans-[Pt(pzhXr] (pz = pyrazine; X = Cl, Br, I, N02) are discussed. Assignments for internal l&and modes are based on the effects of ligand deuteration. Assignments of metal-l&and modes are based on the effects of halide substitu