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Study of model esterifications and of polyesterifications catalyzed by various organometallic derivatives—III. Kinetic and mechanistic study of eterifications catalyzed by tetrabutoxytitanium or zirconium

✍ Scribed by François Leverd; Alain Fradet; Ernest Maréchal

Book ID: 103074205
Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 309 KB
Volume: 23
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(87)90180-7

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Kinetics of oxidation of diethylamine (DEA) by Bromamine-B (BAB) has been investigated at in acid solution with Ru(III) as catalyst. The oxidation behavior obeys 303 K the rate law, rate ϭ k [BAB] [DEA] [Ru(III)] [H ϩ ] Ϫx where 'x' is less than unity indicating retardation of rate by [H ϩ ]. Added