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Kinetic and mechanistic studies of the iridium(III) catalyzed oxidation of sulphanilic acid by diperiodatocuprate(III) in aqueous alkaline medium

✍ Scribed by Munavalli, Deepak S. ;Naik, Praveen N. ;Chimatadar, Shivamurti A. ;Nandibewoor, Sharanappa T.

Publisher: Springer
Year: 2008
Tongue: English
Weight: 149 KB
Volume: 94
Category: Article
ISSN: 0133-1736
DOI: 10.1007/s11144-008-5351-1

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## Abstract The kinetics of oxidation of vanillin (VAN) by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of 0.50 mol dm^−3^ was studied spectrophotometrically. The reaction between DPC and vanillin in alkaline medium exhibits 1:2 stoichiometry (vanillin: DPC). The re

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