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Mechanistic studies of uncatalyzed and ruthenium(III)-catalyzed oxidation of the antibiotic drug chloramphenicol by hexacyanoferrate(III) in aqueous alkaline medium: a comparative kinetic study

✍ Scribed by Meti, M. D.; Byadagi, K. S.; Nandibewoor, S. T.; Chimatadar, S. A.


Book ID
125350246
Publisher
Springer Vienna
Year
2014
Tongue
English
Weight
738 KB
Volume
145
Category
Article
ISSN
0026-9247

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Mechanistic aspects of uncatalyzed and r
✍ Jyothi C. Abbar; Shweta J. Malode; Sharanappa T. Nandibewoor πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 976 KB

The oxidation of dl-ornithine monohydrochloride (OMH) by diperiodatocuprate(III) (DPC) has been investigated both in the absence and presence of ruthenium(III) catalyst in aqueous alkaline medium at a constant ionic strength of 0.20 mol dm -3 spectrophotometrically. The stiochiometry was same in bot