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Ruthenium(III)-catalyzed oxidation of amides by sodium N-bromobenzenesulphonamide in hydrochloric acid: a kinetic and mechanistic study

✍ Scribed by Putta Swamy; Rangegowda Ramachandrappa; Hulivana Ramalingaiah


Book ID
110244432
Publisher
Springer
Year
1999
Tongue
English
Weight
131 KB
Volume
24
Category
Article
ISSN
0340-4285

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## Abstract Kinetics of uncatalyzed and Ru(III)‐catalyzed oxidations of mono‐, di‐, and tri‐chloroacetic acids by the title compound (bromamine‐B or BAB) in HCl medium has been studied at 40Β°C. The uncatalyzed reaction shows a first‐order dependence of the rate on [BAB], and fractional and zero ord