✦ LIBER ✦

Ruthenium (III)-catalyzed oxidative cleavage of phenylpropanolamine withN-bromosuccinimide in hydrochloric acid medium: a kinetic and mechanistic approach

✍ Scribed by K. N. Mohana; K. R. Ramya; P. M. Ramdas Bhandarkar

Publisher: Springer-Verlag
Year: 2010
Tongue: English
Weight: 349 KB
Volume: 100
Category: Article
ISSN: 1878-5190
DOI: 10.1007/s11144-010-0199-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Ruthenium (III)-catalyzed oxidative clea

Ruthenium (III)-catalyzed oxidative cleavage of thiamine hydrochloride with N-bromosuccinimide in presence of hydrochloric acid medium: A kinetic and mechanistic approach

✍ K.N. Mohana; K.R. Ramya 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 523 KB

The kinetics of ruthenium (III)-catalyzed oxidative cleavage of thiamine hydrochloride (THM, Vitamin B 1 ) with N-bromosuccinimide (NBS) in HCl medium has been investigated at 308 K. The oxidation reaction follows the rate law, , where a, b, c and d are less than unity. The stiochiometry of the rea

Ruthenium(III) catalyzed kinetics of chl

Ruthenium(III) catalyzed kinetics of chloroacetic acids oxidation by sodium N-bromobenzenesulfonamide in hydrochloric acid medium

✍ S. Ananda; B. M. Venkatesha; D. S. Mahadevappa; N. M. Made Gowda 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 690 KB

## Abstract Kinetics of uncatalyzed and Ru(III)‐catalyzed oxidations of mono‐, di‐, and tri‐chloroacetic acids by the title compound (bromamine‐B or BAB) in HCl medium has been studied at 40°C. The uncatalyzed reaction shows a first‐order dependence of the rate on [BAB], and fractional and zero ord

Ruthenium(III) – catalyzed oxidative cle

Ruthenium(III) – catalyzed oxidative cleavage ofp-aminoazobenzene by chloramine-B in alkaline medium and uncatalyzed reaction in acid medium: spectrophotometric kinetic and mechanistic study

✍ Puttaswamy; J. P. Shubha; R. V. Jagadeesh 📂 Article 📅 2007 🏛 Springer 🌐 English ⚖ 422 KB

Ruthenium(III)-catalyzed oxidation of 2-

Ruthenium(III)-catalyzed oxidation of 2-phenylethylamine with sodium N-chlorobenzenesulphonamide in hydrochloric acid solution: A kinetic and mechanistic study

✍ K.N. Mohana; N. Prasad 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 488 KB

The kinetics of ruthenium(III)-catalyzed oxidation of 2-phenylethylamine (PEA) with sodium N-chlorobenzenesulphonamide or chloramine-B (CAB) in hydrochloric acid solution has been studied at 313 K. The reaction rate shows first-order dependence each on [CAB], [H + ] and [Ru(III)Cl 3 ] and fractional

Ruthenium(III)-catalyzed and uncatalyzed

Ruthenium(III)-catalyzed and uncatalyzed kinetic studies on the oxidation of sulfanilic acid by chloramine-T in perchloric acid medium: a mechanistic approach

✍ Puttaswamy; Jayachamarajapura Pranesh Shubha 📂 Article 📅 2008 🏛 Springer 🌐 English ⚖ 443 KB

Ru(III)-Catalyzed Oxidation of Some Amin

Ru(III)-Catalyzed Oxidation of Some Amines by Chloramine-T in Hydrochloric Acid Medium — Mechanistic Aspects and Kinetic Modeling

✍ K. N. Shivananda; R. V. Jagadeesh; Puttaswamy Puttaswamy; K. N. Mahendra 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 11 KB