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Ruthenium(III) – catalyzed oxidative cleavage ofp-aminoazobenzene by chloramine-B in alkaline medium and uncatalyzed reaction in acid medium: spectrophotometric kinetic and mechanistic study

✍ Scribed by Puttaswamy; J. P. Shubha; R. V. Jagadeesh


Publisher
Springer
Year
2007
Tongue
English
Weight
422 KB
Volume
32
Category
Article
ISSN
0340-4285

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✍ Jyothi C. Abbar; Shweta J. Malode; Sharanappa T. Nandibewoor 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 976 KB

The oxidation of dl-ornithine monohydrochloride (OMH) by diperiodatocuprate(III) (DPC) has been investigated both in the absence and presence of ruthenium(III) catalyst in aqueous alkaline medium at a constant ionic strength of 0.20 mol dm -3 spectrophotometrically. The stiochiometry was same in bot