## Abstract Kinetics of uncatalyzed and Ru(III)‐catalyzed oxidations of mono‐, di‐, and tri‐chloroacetic acids by the title compound (bromamine‐B or BAB) in HCl medium has been studied at 40°C. The uncatalyzed reaction shows a first‐order dependence of the rate on [BAB], and fractional and zero ord
Ruthenium(III)-catalyzed oxidation of substituted ethanols by sodium N-bromo-p-toluenesulfonamide in hydrochloric acid medium
✍ Scribed by Putta Swamy; Rangegowda Ramachandrappa
- Book ID
- 110244007
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 137 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0340-4285
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The kinetics of oxidation of benzhydrol and its p-substituted derivatives (YBH, where Cl, Br, NO 2 , CH 3 , and OCH 3 ) by sodium N-chloro-p-toluenesulfonamide or chlor-Y ϭ H, amine-T (CAT), catalyzed by ruthenium(III) chloride, in the presence of hydrochloric acid in 30% (v/v) MeOH medium has been
## Abstract Kinetics of oxidation of α ‐amino acids, glycine, valine, alanine, and phenylalanine, by sodium N‐chloro‐__p__‐toluenesulfonamide or chloramine‐T (CAT) has been investigated in HClO~4~ medium at 30°C. The rate shows first‐order dependence on both CAT and amino acid concentrations and an
The kinetics of ruthenium(III)-catalyzed oxidation of 2-phenylethylamine (PEA) with sodium N-chlorobenzenesulphonamide or chloramine-B (CAB) in hydrochloric acid solution has been studied at 313 K. The reaction rate shows first-order dependence each on [CAB], [H + ] and [Ru(III)Cl 3 ] and fractional