The kinetics of oxidation of benzhydrol and its p-substituted derivatives (YBH, where Cl, Br, NO 2 , CH 3 , and OCH 3 ) by sodium N-chloro-p-toluenesulfonamide or chlor-Y ฯญ H, amine-T (CAT), catalyzed by ruthenium(III) chloride, in the presence of hydrochloric acid in 30% (v/v) MeOH medium has been
Kinetic and mechanistic studies of some aliphatic amines' oxidation by sodium N-bromo-p-toluenesulfonamide in hydrochloric acid medium
โ Scribed by S. Ananda; M. B. Jagadeesha; Puttaswamy; B. M. Venkatesha; T. K. Vinod; N. M. Made Gowda
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 154 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0538-8066
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The kinetics of oxidation of the aliphatic primary amines, n-propylarnine, n-butylarnine, and isoarnylarnine, by sodium N-brornobenzenesulfonarnide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35" C The reaction rate shows a First-order dependence each on [ BABl and [amine]. a
The kinetics of oxidation of Norfloxacin [1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(lpiperazinyl)-3-quinoline carboxylic acid] by chloramine-B and N-chlorobenzotriazole has been studied in aqueous acetic acid medium (25% v/v) in the presence of perchloric acid at 323 K. For both the oxidants, the reacti