Studies on the stereoselective hydroboration of vinyl ethers
β Scribed by Glenn J. McGarvey; Joginder S. Bajwa
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 201 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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## Abstract For Abstract see ChemInform Abstract in Full Text.
A general, stereoselective approach to vinyl ethers from ~-alkoxyaldehydes is described which features a stereocontrolled tri-~-butylstannyl addition/ elimination sequence.
The electron diffraction data of gaseous methyl vinyl ether shows, in agreement with recent spectroscopic investigations, that the compound exists in two conformations, the most stable one being the cis form. The second conformer has a non-planar heavy atom skeleton, and the angle between the C=C-0