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On the structure of gaseous methyl vinyl ether

✍ Scribed by N.L. Owen; H.M. Seip

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
223 KB
Volume
5
Category
Article
ISSN
0009-2614

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✦ Synopsis

The electron diffraction data of gaseous methyl vinyl ether shows, in agreement with recent spectroscopic investigations, that the compound exists in two conformations, the most stable one being the cis form. The second conformer has a non-planar heavy atom skeleton, and the angle between the C=C-0 and *the C-O-C planes (a) is in the range 80-llO". The energy difference is about 1.2 kcal/mole.

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