𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Stereoselective synthesis of vinyl ethers from α-alkoxyaldehydes

✍ Scribed by Glenn J. McGarvey; Masayuki Kimura; Andrew Kucerovy


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
167 KB
Volume
26
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


A general, stereoselective approach to vinyl ethers from ~-alkoxyaldehydes is described which features a stereocontrolled tri-~-butylstannyl addition/ elimination sequence.


📜 SIMILAR VOLUMES


A novel synthesis of allyl vinyl ethers
✍ J.C. Gilbert; U. Weerasooriya; B. Wiechman; L. Ho 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 251 KB

Base-promoted reaction of dimethyt d~usomet~~zp~sp~~te (21 with aZipkatic ketones -in the presence of aZlylie alcohols affords aldehydio atlyZ vi?fyZ ethers (:I. Ally1 vinyl ethers, 4, are of interest because they undergo the Claisen rearrangement, 2 a sequence that accomplishes net a-allylation of