A Stereoselective synthesis of vinyl ethers from α-alkoxyaldehydes
✍ Scribed by Glenn J. McGarvey; Masayuki Kimura; Andrew Kucerovy
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 167 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
A general, stereoselective approach to vinyl ethers from ~-alkoxyaldehydes is described which features a stereocontrolled tri-~-butylstannyl addition/ elimination sequence.
📜 SIMILAR VOLUMES
BF3.Et20 or Yb(OTf)3 catalyzed [4+2] cycloaddition reaction of ct-CF3-N-arylaldimines with nucleophilic olefins afforded CF3-substituted tetrahydroquinoline derivatives.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Base-promoted reaction of dimethyt d~usomet~~zp~sp~~te (21 with aZipkatic ketones -in the presence of aZlylie alcohols affords aldehydio atlyZ vi?fyZ ethers (:I. Ally1 vinyl ethers, 4, are of interest because they undergo the Claisen rearrangement, 2 a sequence that accomplishes net a-allylation of