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Studies on Lactams. III. 1 Mechanism of Cyclization

✍ Scribed by BOSE, AJAY K.; MANHAS, M. S.

Book ID
120647106
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
596 KB
Volume
27
Category
Article
ISSN
0022-3263

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Ξ²-Lactam synthesis: Cyclization versus 1
Ξ²-Lactam synthesis: Cyclization versus 1,2-acyl migration-cyclization. The mechanism of the 1,2-acyl migration-cyclization
✍ Jollie D Godfrey Jr.; Richard H Mueller; Derek J Von Langen πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 218 KB

The cyclization of hydroxamate 1 unexpectedly afforded two isomeric @lactams 2 and 1. The mechanism for the formation of 2 has been shown by carbon-13 labeling to involve a novel 1,2-acyl migration-cyclization process.