Electrochemical studies on ฮฒ-lactams. Pa
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Maria Antonietta Casadei; Achille Inesi; Franco Micheletti Moracci; Donatella Oc
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Article
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1989
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Elsevier Science
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French
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Electroreduction of 3-bromo-and 3,3-dichloro-JMzctams 1 carried out at the potential of the first voltammetricpeak andin thepresence of acetic anhydridegives3-acetyl-#-lactams2. The electrosynthesis is highly stereoselective, as only the acetyl derivative with trans co@iguration is formed.