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Electrochemical studies on ?-lactams. Part 1. Electroreduction of 3-halogeno-?-lactams

โœ Scribed by Casadei, Maria Antonietta; Moracci, Franco Micheletti; Inesi, Achille


Book ID
119995271
Publisher
Royal Society of Chemistry
Year
1986
Tongue
English
Weight
745 KB
Volume
3
Category
Article
ISSN
1472-779X

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Electrochemical studies on ฮฒ-lactams. Pa
โœ Maria Antonietta Casadei; Achille Inesi; Franco Micheletti Moracci; Donatella Oc ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 547 KB

Electroreduction of 3-bromo-and 3,3-dichloro-JMzctams 1 carried out at the potential of the first voltammetricpeak andin thepresence of acetic anhydridegives3-acetyl-#-lactams2. The electrosynthesis is highly stereoselective, as only the acetyl derivative with trans co@iguration is formed.