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Studies on lactams. Part XVI. Stereochemistry of β-lactam formation

✍ Scribed by Ajay K. Bose; G. Spiegelman; M.S. Manhas


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
164 KB
Volume
12
Category
Article
ISSN
0040-4039

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Electrochemical studies on β-lactams. Pa
✍ Maria Antonietta Casadei; Achille Inesi; Franco Micheletti Moracci; Donatella Oc 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 547 KB

Electroreduction of 3-bromo-and 3,3-dichloro-JMzctams 1 carried out at the potential of the first voltammetricpeak andin thepresence of acetic anhydridegives3-acetyl-#-lactams2. The electrosynthesis is highly stereoselective, as only the acetyl derivative with trans co@iguration is formed.