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Studies directed toward the total synthesis of the rubradirin antibiotics. 4. A new Diels-Alder—Claisen effective diene

✍ Scribed by Alan P. Kozikowski; Kiyoshi Sugiyama; Edward Huie

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
211 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

Summahq: A new diene ban been nqnthekzed which eddective&q cvupLen Xthe V.ie&-ALdeh fieaction u&h the CL&en h eahrtauzgement.

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The carboxylic acid antibiotic A-23187 (A) is a divalent cation ionophore which has been isolated from cultures of Streptomyces chartreusensis.' The structure and proposed absolute configuration2 have shown it to be one of a limited group of natural products, including oligomycin B3 and aplysiatoxin