Studies directed toward the synthesis of adriamycin: diels-alder reactions of anthradiquinones and various dienes
β Scribed by T. Ross Kelly; Richard N. Goerner Jr.; John W. Gillard; Barbara K. Prazak
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 320 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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Summahq: A new diene ban been nqnthekzed which eddective&q cvupLen Xthe V.ie&-ALdeh fieaction u&h the CL&en h eahrtauzgement.
Photoinduced electron transfer (PET) initiates radical-cation Diels Β± Alder reactions between indole and exocyclic dienes. As catalysts, triarylpyrylium tetrafluoroborates are used. The products are [b]-anellated tetrahydrocarbazoles, which are not accessible through neutral cycloadditions. The resu
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