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Structure of trans-carbonylchlorobis(tri-p-tolylphosphine)iridium(I)

✍ Scribed by Churchill, M. R. ;Fettinger, J. C. ;Rappoli, B. J. ;Atwood, J. D.


Book ID
114504615
Publisher
International Union of Crystallography
Year
1987
Tongue
English
Weight
366 KB
Volume
43
Category
Article
ISSN
0108-2701

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Iodo­tris(tri-p-tolyl­phosphine)silver(I
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In the title compound, [AgI(C 21 H 21 P) 3 ], important bond distances are: Ag-P = 2.5346 (9), 2.5562 (9) and 2.5617 (9) A ˚, and Ag-I = 2.8683 (5) A ˚. The Ag I atom is in a distorted tetrahedral environment and all bond angles are close to the ideal values.

Tetra­kis(tri-p-tolyl­phosphine-κP)silve
✍ Venter, Gertruida J. S. ;Meijboom, Reinout ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.007 A R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.