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trans-Carbonylchlorobis(tricyclohexylphosphine)iridium(I)

✍ Scribed by Kuwabara, E. ;Bau, R.

Book ID: 114511242
Publisher: International Union of Crystallography
Year: 1994
Tongue: English
Weight: 332 KB
Volume: 50
Category: Article
ISSN: 0108-2701
DOI: 10.1107/s0108270194004774

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The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1