In the title compound, [Ru(C 4 H 3 N 2 S) 2 (C 18 H 15 P) 2 ]ÁCHCl 3 , the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecularinteractions between the pyrimidine and
Structure of bromo(trimethylsilylethynyl)bis(triphenylphosphine)palladium(II)–chloroform–dichloromethane (2/2/1) solvate
✍ Scribed by van der Voort, E. ;Spek, A. L. ;de Graaf, W.
- Book ID
- 114504375
- Publisher
- International Union of Crystallography
- Year
- 1987
- Tongue
- English
- Weight
- 361 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]Á-CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakaji
The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize