In the title complex, [Rh(acac)(CO)(PCy 2 Ph)] (acac = acetylacetonate, Cy = cyclohexyl) or [Rh(C 5 H 7 O 2 )(CO)-(C 18 H 27 P)], the Rh atom is coordinated by one P [Rh-P = 2.2424 (9) A ˚], two O [Rh-O = 2.0783 (17) and 2.0411 (18) A ˚] and one C [Rh-C = 1.797 (3) A ˚] atoms in a slightly distorted
✦ LIBER ✦
Structure of acetylacetonato(carbonyl)bis(tricyclohexylphosphine)rhodium(I)
✍ Scribed by Ansell, G. B. ;Leta, S. ;Oswald, A. A. ;Mozeleski, E. J.
- Book ID
- 114503447
- Publisher
- International Union of Crystallography
- Year
- 1986
- Tongue
- English
- Weight
- 319 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0108-2701
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The title compound, [Rh(C~5~H~7~O~2~)(C~18~H~21~P)(CO)], has the acetylacetonate-chelated Rh^I^ atom in a square-planar geometry. Intramolecular C—H...O hydrogen bonds exist between the acetylacetonate group and the cyclohexyl ring, resulting in a buckling of the acetylacetonate skeleton. Molecules