Structure of (1,10-phenanthroline)bis(4-toluenethiolato)zinc(II)
✍ Scribed by Cremers, T. L. ;Bloomquist, D. R. ;Willett, R. D. ;Crosby, G. A.
- Book ID
- 114527404
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 322 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand o
An N 2 S 2 -donor set de®nes the approximately tetrahedral coordination environment about the zinc centre in the monomeric title compound, [Zn(S 2 CO i Pr) 2 (4,7-Me 2 phen)] or [Zn(C 4 H 7 OS 2 ) 2 (C 14 H 12 N 2 )], which has crystallographically imposed twofold rotation symmetry.