The relative configuration and stereochemistry of spiroepoxides prepared by dimethyldioxirane, alkaline hydrogen peroxide and m-chloroperoxybenzoic acid and of dione by-products were elucidated by various 'H and 13C NMR methods.
Structure Elucidation of the Photooxygenation Products of 1,2-Dihydronaphthalenes
✍ Scribed by Gábor Tóth; Torsten Linker; Frank Rebien
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 304 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Photooxygenation of 1,2-dihydronaphthalenes resulted in diendoperoxides and hydroperoxides via [ 4 + 2 ] cycloaddition and ene reactions, respectively. The relative conÐguration and stereochemistry of the products were elucidated by various 1H and 13C NMR methods.
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