Photooxygenation of 1,2-dihydronaphthalenes resulted in diendoperoxides and hydroperoxides via [ 4 + 2 ] cycloaddition and ene reactions, respectively. The relative conÐguration and stereochemistry of the products were elucidated by various 1H and 13C NMR methods.
Structure Elucidation of the Oxidation Products of 2-Arylidene-1-indanones and 2-Arylidene-1-benzosuberones
✍ Scribed by Gábor Tóth; Judit Halász; Sándor Boros; Albert Lévai; Csaba Nemes; Tamás Patonay
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 410 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
The relative configuration and stereochemistry of spiroepoxides prepared by dimethyldioxirane, alkaline hydrogen peroxide and m-chloroperoxybenzoic acid and of dione by-products were elucidated by various 'H and 13C NMR methods.
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