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The Mass Spectral Analyses of 2-Sila-1,2-dihydronaphthalene Derivatives

✍ Scribed by Taewook Kim; Chang Hwan Kim; Myong Euy Lee; Dae-Jei Bang; Soo-Dong Yoh; Young-Woo Kwak

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 412 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(199604)10:6<627::aid-rcm431>3.0.co;2-n

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✦ Synopsis

Mass spectral analyses of 2-sila-l,2-dihydronaphthalene derivatives are reported. The 2-silanaphthalene radical cations, Zsilanaphthyl cation, 1-sifaindenyl cation, indene radical cation, and indenyl cation were proposed among the fragments of these molecules. The important fragmentation pathways consist of @-elimination of a molecule which includes the substituent on silicon, elimination of carbenes and elimination of silylenes.

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