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Structural information from OH stretching frequencies—V. On the presence of different rotamers in substituted tertiary cyclohexanol compounds

✍ Scribed by E.T.G. Lutz; J.H. Van der Maas


Book ID
113374504
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
476 KB
Volume
36
Category
Article
ISSN
1386-1425

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Structural information from OH stretchin
✍ E.T.G. Lutz; J.H. van der Maas 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 520 KB

The presence. of different hydroxyl rotamers in alkyl substituted tertiary adamantanol-2 and bicyclo[3.3.l]nonanol-9 compounds has been studied in Ccl, solution by means of the i.r. absorption of the OH-stretching band. The rotamer with the OH positioned over the ring skeleton proves to be sensitive