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Structural information from OH stretching frequencies—XI. The orientation of the hydroxyl group in tertiary α-ethynyl alcohols

✍ Scribed by T. Visser; J.H. Van der Maas


Book ID
108007149
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
416 KB
Volume
39
Category
Article
ISSN
1386-1425

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Structural information from OH-stretchin
✍ T. Visser; J.H. van der Maas 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 376 KB

presence ofdifferent OH-rotamers in 18 hydroxy steroids dissolved in Ccl, has been studied by means of the i.r. absorption band. In compounds with a triple bond at the same C-atom as to which the hydroxyl group is attached, the OH appears to be present in only one rotamer position, viz. next to the