Structural information from OH stretching frequencies—IX. The influence of γ-alkyl substituents on the different OH rotamers in saturated axial cyclohexanols

Structural information from OH stretchin

Structural information from OH stretching frequencies—VI. On the presence of different rotamers in alkyl substituted tertiary adamantanol-2 and bicylo[3.3.1]nonanol-9 compounds

✍ E.T.G. Lutz; J.H. van der Maas 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 520 KB

The presence. of different hydroxyl rotamers in alkyl substituted tertiary adamantanol-2 and bicyclo[3.3.l]nonanol-9 compounds has been studied in Ccl, solution by means of the i.r. absorption of the OH-stretching band. The rotamer with the OH positioned over the ring skeleton proves to be sensitive