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Structural information from OH stretching frequencies—X. OH-rotamer distribution in axial tertiary cyclohexanols

✍ Scribed by J.H. Van der Maas; E.T.G. Lutz

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
364 KB
Volume
38
Category
Article
ISSN
1386-1425

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Structural information from OH stretchin
Structural information from OH stretching frequencies—VI. On the presence of different rotamers in alkyl substituted tertiary adamantanol-2 and bicylo[3.3.1]nonanol-9 compounds
✍ E.T.G. Lutz; J.H. van der Maas 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 520 KB

The presence. of different hydroxyl rotamers in alkyl substituted tertiary adamantanol-2 and bicyclo[3.3.l]nonanol-9 compounds has been studied in Ccl, solution by means of the i.r. absorption of the OH-stretching band. The rotamer with the OH positioned over the ring skeleton proves to be sensitive