Structural and spectroscopic characterization of bis(thiosaccharinato)bis(benzimidazole)cadmium(II)
✍ Scribed by S.H. Tarulli; O.V. Quinzani; O.E. Piro; E.E. Castellano; E.J. Baran
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 135 KB
- Volume
- 797
- Category
- Article
- ISSN
- 0022-2860
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In the title compound, [Cd(C 7 H 5 O 3 ) 2 (C 7 H 6 N 2 ) 2 ]ÁH 2 O, the Cd II ion is surrounded by two salicylate anions and two benzimidazole molecules in a strongly distorted octahedral cis-CdN 2 O 4 geometry. The partially overlapped arrangement and the face-to-face distances of 3.22 (3) and 3.3
The Cd^II^ ion of the title mononuclear complex, [Cd(C~12~H~9~O~2~)~2~(C~7~H~6~N~2~)~2~]·H~2~O, lies on a crystallographic twofold rotation axis and is in a distorted trigonal prismatic coordination enivironment, involving four carboxylate O atoms from two chelating naphthaleneacetate ligands and tw