Bis(μ-3-carboxylatophenoxyacetato)bis[aquabis(1H-benzimidazole)cadmium(II)] dihydrate
✍ Scribed by Zhao, Hui ;Huo, Li-Hua ;Gao, Shan ;Zhao, Jing-Gui
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 261 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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The dicarboxylate ligand in the title compound, [Mn(C 9 H 6 -O 5 )(C 12 H 8 N 2 ) 2 (H 2 O)]Á4H 2 O, coordinates in a monodentate manner to the Mn II atom through the carboxylate group on the benzene ring. The two O atoms in the octahedral configuration around the Mn II atom are cis to each other. E
In the title one-dimensional polymer, {[Zn(3-CPOA)-(C 3 H 4 N 2 ) 2 ]Á3H 2 O} n (3-CPOA 2À is the 3-carboxylatophenoxyacetate dianion, C 9 H 6 O 5 ), the Zn atom shows tetrahedral coordination, as it is linked to two N atoms from two imidazole molecules and two carboxylate O atoms from two different
The Cd^II^ ion of the title mononuclear complex, [Cd(C~12~H~9~O~2~)~2~(C~7~H~6~N~2~)~2~]·H~2~O, lies on a crystallographic twofold rotation axis and is in a distorted trigonal prismatic coordination enivironment, involving four carboxylate O atoms from two chelating naphthaleneacetate ligands and tw
In the title complex, [Cd(NO~3~)~2~(C~20~H~14~N~4~)~2~]·2H~2~O, the Cd^II^ ion, which lies on a crystallographic twofold axis, is bis-chelated by two nitrate ligands and is coordinated by one tertiary N atom from each of two 1,3-bis(1__H__-benzimidazol-2-ylmethyl)benzene ligands in a distorted octah
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.006 A R factor = 0.035 wR factor = 0.095 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.