𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase. Ethylene

✍ Scribed by Herron, John T.; Huie, Robert E.


Book ID
127276247
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
725 KB
Volume
99
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Stopped-flow studies of the mechanisms o
✍ John T. Herron; Robert E. Huie πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 894 KB

The reactions of ozone with propene and isobutene have been studied in the gas phase at 298'K and 530 Pa (4 torr) using a stopped-flow reactor coupled to a photoionization mass spectrometer. Reactant and product concentrations were followed as a function of reaction time. The major reaction products

Stopped-flow study of the gas-phase reac
✍ Richard I. Martinez; John T. Herron πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 231 KB

The autocat& trc reactron of ozone u~th rhr~rane has been studled at 296 K and 1 1 kPa (8 Torr) The spenfic rate of pnmar) attack of ozone on thrrrane LS Immeasurably slow (X-< 10' cm3 mol-' s-' )-The maJor products observed are CzH4, SOz. H2CO and COz. A free-rarhcal cham mcchamsm IS suggested to a

The kinetics of the gas-phase reaction b
✍ Erina S. Toby; Sidney Toby; H. Edward O'Neal πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 460 KB πŸ‘ 2 views

The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti