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Stopped-flow study of the gas-phase reactions of ozone with organic sulfides: thiirane

โœ Scribed by Richard I. Martinez; John T. Herron

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
231 KB
Volume
72
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The autocat& trc reactron of ozone u~th rhr~rane has been studled at 296 K and 1 1 kPa (8 Torr) The spenfic rate of pnmar) attack of ozone on thrrrane LS Immeasurably slow (X-< 10' cm3 mol-' s-' )-The maJor products observed are CzH4, SOz. H2CO and COz. A free-rarhcal cham mcchamsm IS suggested to account for these observatrons

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