Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase: trans-2-butene
β Scribed by Martinez, Richard I.; Herron, John T.
- Book ID
- 126609134
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 548 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0022-3654
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The reactions of ozone with propene and isobutene have been studied in the gas phase at 298'K and 530 Pa (4 torr) using a stopped-flow reactor coupled to a photoionization mass spectrometer. Reactant and product concentrations were followed as a function of reaction time. The major reaction products
The autocat& trc reactron of ozone u~th rhr~rane has been studled at 296 K and 1 1 kPa (8 Torr) The spenfic rate of pnmar) attack of ozone on thrrrane LS Immeasurably slow (X-< 10' cm3 mol-' s-' )-The maJor products observed are CzH4, SOz. H2CO and COz. A free-rarhcal cham mcchamsm IS suggested to a