Hydrolysis and methanolysis of Avilamycin C yielded a series of mono‐ and oligosaccharide‐like products, which were, with one exception, identical with degradation products of flambamycin. Instead of evalose (6‐deoxy‐3‐methyl‐D‐mannose), a building stone of Flambamycin and Everninomicin B, evermicos
Stoffwechselprodukte von Mikroorganismen. 210. Mitteilung. Über die Avilurekanosen A and C and weitere Abbauprodukte Avilamycine A and C
✍ Scribed by Ernst Kupfer; Katarina Neupert-Laves; Max Dobler; Walter Keller-Schierle
- Book ID
- 102856651
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- German
- Weight
- 554 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
The Avileurekanoses A and C and Further Degradation Products of the Avilamycins A and C
Alkaline hydrolysis of the orthosomycin antibiotics, avilamycins A ad C products similar t those earlier described for flambamycin. Among these avileurekanose c (15) became of particular importance because its acetate prisms suitable for an X‐ray structural determination. For the avilamycins A and C structural formulae 2 and 3, respectively, can now be drawn, in which only the configuration at C (16), one out of 32 asymmetric C‐atoms, is not yet determined.
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