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Stoffwechselprodukte von Mikroorganismen 6-Chlorgenistein und 6,3′-Dichlorgenistein. 164. Mitteilung

✍ Scribed by W. A. König; C. Krauss; H. Zähner


Publisher
John Wiley and Sons
Year
1977
Tongue
German
Weight
348 KB
Volume
60
Category
Article
ISSN
0018-019X

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✦ Synopsis


Metabolites from Microorganisms, 6‐Chlorogenistein and 6,3′‐Dichlorogenistein

A strain of Streptomyces griseus produced chlorinated metabolites in media containing soybean meal. Two of these metabolites were isolated together with a chlorine free compound which could be identified as the isoflavone genistein (I) by its spectral properties and by comparison with an authentic sample. By NMR. and mass spectroscopy the chlorinated compounds were shown to be 6‐chlorogenistein (II) and 6,3′‐dichlorogenistein (III).

The 7‐glucoside of genistein is a constituent of soybean meal; it is hydrolysed and chlorinated by Streptomyces griseus.


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