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Sterically Demanding Chelating Diamide Complexes of Yttrium and Lutetium

โœ Scribed by Roesky, Peter W.

Book ID
127212253
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
119 KB
Volume
21
Category
Article
ISSN
0276-7333

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The chelating diamide complexes (BDAPIZr-(NMed2 (21, (BDAP)ZrClz(pyh (4), (BDAP)ZrR2 (5a, R = CH2Ph; 5b, R = Me), (BDAP) Zr(l;15-Cp)C1 (5c), and(BDAP)Zr(rl2(N,C)-NC5H4)(CH2CMe2Ph) (5d) (BDAP = ArNCH2CH2CHJLAr; Ar = 2,6-iPr~-Cd-โ‚ฌ3) have been prepared. An X-ray study of (BDAP)Zrf$(N,C)-NC5H4)-( CH2CMe