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Aluminium Complexes of a Sterically Demanding Bis(iminophosphorane)methandiide

✍ Scribed by Sindlinger, Christian P.; Stasch, Andreas


Book ID
121861870
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
2013
Tongue
English
Weight
640 KB
Volume
66
Category
Article
ISSN
0004-9425

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First-Row Transition Metal Bis(amidinate
✍ Christian A. Nijhuis; Erica Jellema; Timo J. J. Sciarone; Auke Meetsma; Peter H. πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 198 KB

## Abstract The sterically hindered benzamidinate ligand [PhC(NAr)~2~]^–^ (Ar = 2,6‐__i__Pr~2~C~6~H~3~) has been employed to prepare bis(amidinate) complexes [{PhC(NAr)~2~}~2~M] of the divalent first‐row transition metals Cr–Ni (1–5). For Cr (planar), Mn and Co (tetrahedral) the observed structures