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Transition Metal Complexes with Sterically Demanding Ligands. 2. 1 Meisenheimer Complex Formation and Deprotonation Reactions of a Sterically Demanding Aromatic Diimine †

✍ Scribed by Nückel, Stefan; Burger, Peter

Book ID: 126776733
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 150 KB
Volume: 19
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om000084k

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## Abstract The two macrocycles 1‐(2‐aminoethyl)‐ and 1‐[2‐(dimethylamino)ethyl]‐4, 8, 11‐trimethyl‐1, 4, 8, 11‐tetraazacyclotetradecane, **1** and **2**, respectively, and their metal complexes with Co^2+^, Ni^2+^ and Cu^2+^ were prepared. The different spectral properties of the complexes with th