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(Diphenylphosphinoethyl)cyclopentadienyl complexes of yttrium and lutetium: synthesis and structure

✍ Scribed by D. M. Roitershtein; A. V. Romanenkov; K. A. Lyssenko; P. A. Belyakov; M. Yu. Antipin

Book ID
106520607
Publisher
Springer
Year
2007
Tongue
English
Weight
300 KB
Volume
56
Category
Article
ISSN
1573-9171

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The stepwise reaction of Me 2 SiCl 2 with K[C 5 H 3 t BuMe-3] or Li[C 9 H 7 ] and then with K[C 9 H 6 CH 2 CH 2 -NMe 2 -1] followed by double deprotonation with NaH or LiBu, yields the two dimethylsilicon bridged cyclopentadienyl-indenyl and indenyl-indenyl donor-functionalized ligand systems K 2 ),