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Stereoselective Total Synthesis of 5(S), 6(R), 15(S)-Trihydroxy-7(E), 9(E), 11(Z),13(E)-Eicosatetraenoic Acid (Lipoxin A)

โœ Scribed by J.S Yadav; D.K Barma; Dinah Dutta

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
418 KB
Volume
39
Category
Article
ISSN
0040-4039

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A stereoselective and practical synthesi
A stereoselective and practical synthesis of 5,6(S,S)-epoxy-15(S)-hydroxy-7(E),9(E),11(Z),13(E)-eicosatetraenoic acid (4), possible precursor of the lipoxins
โœ E.J. Corey; Mukund M. Mehrotra ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 267 KB

A stereoselective synthesis of 4, a possible biosynthetic precursor of lipoxins, is reported. A pathway is suggested by which 4 can give rise to the biologically active lipoxins 1 and 2. In 1984 Serhan, Hamberg and Samuelsson reported that human leukocytes convert 15(S)-