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Stereoselective synthesis of (11R, 12S)-(5Z,7E,9E,14Z)-11, 12-dihydroxy-5,7,9,14-eicosatetraenoic acid from 'Diacetone Glucose'

✍ Scribed by G.V.M. Sharma; S.Mahender Rao

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
138 KB
Volume
35
Category
Article
ISSN
0040-4039

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3Z,6E)-l-Bromododeca-3,6-diene, a common intermediate in the synthesis of labelled 12t linoleic acid and 14t arachidonic acid, was obtained from (E)-3-nonyl-l-ol, in four steps, via conventional functional manipulations. Cross-coupling of this bromododecadiene with the Grignard reagent of l-chloro-5