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Stereoselective synthesis of conjugated all-trans-tetraenes. Application to the synthesis of β-parinaric acid methyl ester

✍ Scribed by Guy Solladié; Chakib Kalaï; Marc Adamy; Françoise Colobert

Book ID
104257923
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
174 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

in this paper is reported the stereoselective synthesis of all-trans-tetraenes by reductive elimination of 1,8-dibenzoate-2,4,6-trienes with sodium amalgam. The method was applied to the syntheses of4E, 6E, BE, 10E-heptatetraene and [~-parinaric acid methyl ester.

📜 SIMILAR VOLUMES

Stereoselective synthesis of all-trans m
Stereoselective synthesis of all-trans methyl substituted polyenes by reductive elimination and application to the synthesis of all-trans 3-methyl-nona-2,4,6-trienol
✍ Guy Solladié; Françoise Colobert; Chakib Kalaı̈ 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 117 KB

The stereoselective synthesis of all-trans 3-methyl-nona-2,4,6-trienol 2 by reductive elimination of the corresponding 1,6-dibenzoate-2-methyl-2(Z),4(Z)-diene is described. This result shows that reductive elimination can be extended to the formation of all-trans methyl substituted polyenes which ar

ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of all-trans Methyl Substituted Polyenes by Reductive Elimination and Application to the Synthesis of all-trans 3-Methyl-nona-2,4,6-trienol.
✍ Guy Solladie; Francoise Colobert; Chakib Kalai 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

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