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Stereoselective synthesis of all-trans methyl substituted polyenes by reductive elimination and application to the synthesis of all-trans 3-methyl-nona-2,4,6-trienol

✍ Scribed by Guy Solladié; Françoise Colobert; Chakib Kalaı̈

Book ID: 104210330
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 117 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00564-5

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✦ Synopsis

The stereoselective synthesis of all-trans 3-methyl-nona-2,4,6-trienol 2 by reductive elimination of the corresponding 1,6-dibenzoate-2-methyl-2(Z),4(Z)-diene is described. This result shows that reductive elimination can be extended to the formation of all-trans methyl substituted polyenes which are present in many natural products biosynthetically made from isoprenic units.

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